So my recommendation if you have not done it before is:-
1) Remove tyre and tube standing on it to get it to release from the rim
2) Insert the new tubless valves. You do need to ensure these seat well (MucOff ones come with a few options for rubber grommits to ensure a tight fit. You don't want to screw the valves in super tight as you want the rubber to fit well without being totally crushed, but do do them up tight as people often find they leak at first
3) I'd then try seating the tyre without putting the sealant in. I found the Smart Sams to be a tight fit on the rim and they inflated easily
4) let the tyres down and remove the valve core (the MucOff tubeless valves come with a handle tool - if you not sure what this is, its basically unscrewing the middle of the valve and removing it leaving just the outer tube)
5) put the sealant in using the tube that comes with the MucOff Sealant bottle through the open valve. I'd put in extra as whilst its a little bit more weight you have en eMTB right so who cares ;-)
6) But the valve core back in and inflate to 40psi, then slosh the sealant around, tapping the tyre on the ground and generally splashing the sealant up the tyre walls inside the tyre
You should be good to go! The reason I do steps 3 and 4 instead of just pouring the sealant into the tyre before you fully seat it, is the Smart Sams were so tight it was a nightmare trying to get it all to seat without the sealant leaking out everywhere

Loads of good videos on Youtube will show you how and you will never look back...