I use Continental Revo sealant. It has a tapered nozzle for injecting down the valve. The bottle has to be shaken of course to get all the particles contained in the sludge at the base of the bottle back into suspension. But when you do, they won't even come out of the nozzle! It's not surprising really. If the sealant is supposed to seal 6mm holes in your tube, why would they flow through a 3mm hole in the end of the nozzle?
It's not just me either, I got my grandson to try it yesterday. My thought was that if it doesn't work it would be a learning experience for him and if it did work, a learning experience for me! He failed as well.
PS: The only time I got sealant down the valve was when I had failed to shake up the bottle first. The next time I got a puncture the latex just pissed out of the hole without sealing. Inner tube time!