@Arethustra
1: Check the motor mounting bolts for tightness. (Check all the other bolts as you would for any new bike).
2: Remove the various covers and remove the battery, just so you know how to do it while the bike is shiny and new. I have a removable battery, but I reckon I have removed it twice (ok, maybe 3 at the most) since I bought it nearly 3 years ago.
3: Familiarise yourself with the display and all the various motor settings. Experiment with them on the trail as you would with new suspension. The settings can make an astounding difference to your ride. One story: It took me less than ten mins to set up a mate's bike such that he was over the moon with it. Prior to that he was going to return it to the shop!
4: Burn your hosepipe and buy a bucket and sponge.
5: Buy a timer.
6: When you return from a ride, charge the battery to somewhere between 50% and 65%. Use your timer. It is not an exact science.
The day before your next ride, set a timer to charge the bike to 100%, with the timer ending an hour before you need it, with a maximum charge of 3 hours. You will soon learn what charge to set. It is not an exact science.
7: Carry out all checks as you would for a normal mtb. Clean and lube, get stuff serviced etc. Check the transmission a bit more frequently.
8: Do Not Worry! The bike is for having fun, if it causes you stress, get rid of it!!